AustralieFrV1, Main, Exploration, bibRecord, 004957

Spin Crossover in a 3,5‐Bis(2‐pyridyl)‐1,2,4‐triazolate‐Bridged Dinuclear Iron(II) Complex [{Fe(NCBH3)(py)}2(μ‐L1)2] – Powder versus Single Crystal Study

Identifieur interne : 004957 ( Main/Exploration ); précédent : 004956; suivant : 004958

Spin Crossover in a 3,5‐Bis(2‐pyridyl)‐1,2,4‐triazolate‐Bridged Dinuclear Iron(II) Complex [{Fe(NCBH3)(py)}2(μ‐L1)2] – Powder versus Single Crystal Study

Auteurs : Caspar J. Schneider ; John D. Cashion [Australie] ; Nicholas F. Chilton ; Céline Etrillard [France] ; Mauricio Fuentealba [Royaume-Uni] ; Judith A. K. Howard [Royaume-Uni] ; Jean-François Létard [France] ; Carsten Milsmann [États-Unis] ; Boujemaa Moubaraki ; Hazel A. Sparkes [Royaume-Uni] ; Stuart R. Batten ; Keith S. Murray [États-Unis]

Source :

European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2013-02-18.

RBID : ISTEX:51A5236732D9FD366F5E79B45EC2C9673EE8A0EE

English descriptors

Abstract

The structural characteristics and physical properties of the 3,5‐bis(2‐pyridyl)‐1,2,4‐triazolate (L1) bridged dinuclear iron(II) spin‐crossover complex [{Fe(NCBH3)(py)}2(μ‐L1)2] (1) in both powder (1p) and single crystal (1c) forms have been investigated. Both forms of [{Fe(NCBH3)(py)}2(μ‐L1)2] display a thermally induced spin transition; however, the transitions have different T1/2 values and different degrees of spin conversion. Both forms display the photomagnetic light‐induced excited spin‐state trapping (LIESST) effect as well as reverse LIESST and have been compared by Raman spectral and powder X‐ray diffraction methods, which indicate that they are polymorphs. The single crystal form 1c shows a “half” spin transition and has been further characterised at temperatures above and below the spin transition by low temperature crystallographic methods including single crystal LIESST experiments (at 40 K) and by Mössbauer spectroscopy; thus, the nature of the [HS‐LS] form and the different spin isomers were revealed. To complement the experimental results, compound 1 and several other related FeII dinuclear spin‐crossover compounds have been evaluated by quantum‐chemical DFT calculations. Additionally, the susceptibilities for the powder form 1p, which displays a complete two‐step spin‐crossover, were also fitted to a phenomenological model for dinuclear spin‐crossover complexes.

Url:

https://api.istex.fr/document/51A5236732D9FD366F5E79B45EC2C9673EE8A0EE/fulltext/pdf

DOI: 10.1002/ejic.201201075

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 000F44
to stream Istex, to step Curation: 000F44
to stream Istex, to step Checkpoint: 000267
to stream Main, to step Merge: 004A81
to stream Main, to step Curation: 004957

Le document en format XML

<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Spin Crossover in a 3,5‐Bis(2‐pyridyl)‐1,2,4‐triazolate‐Bridged Dinuclear Iron(II) Complex [{Fe(NCBH3)(py)}2(μ‐L1)2] – Powder versus Single Crystal Study</title>
<author><name sortKey="Schneider, Caspar J" sort="Schneider, Caspar J" uniqKey="Schneider C" first="Caspar J." last="Schneider">Caspar J. Schneider</name>
</author>
<author><name sortKey="Cashion, John D" sort="Cashion, John D" uniqKey="Cashion J" first="John D." last="Cashion">John D. Cashion</name>
</author>
<author><name sortKey="Chilton, Nicholas F" sort="Chilton, Nicholas F" uniqKey="Chilton N" first="Nicholas F." last="Chilton">Nicholas F. Chilton</name>
</author>
<author><name sortKey="Etrillard, Celine" sort="Etrillard, Celine" uniqKey="Etrillard C" first="Céline" last="Etrillard">Céline Etrillard</name>
</author>
<author><name sortKey="Fuentealba, Mauricio" sort="Fuentealba, Mauricio" uniqKey="Fuentealba M" first="Mauricio" last="Fuentealba">Mauricio Fuentealba</name>
</author>
<author><name sortKey="Howard, Judith A K" sort="Howard, Judith A K" uniqKey="Howard J" first="Judith A. K." last="Howard">Judith A. K. Howard</name>
</author>
<author><name sortKey="Letard, Jean Rancois" sort="Letard, Jean Rancois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name>
</author>
<author><name sortKey="Milsmann, Carsten" sort="Milsmann, Carsten" uniqKey="Milsmann C" first="Carsten" last="Milsmann">Carsten Milsmann</name>
</author>
<author><name sortKey="Moubaraki, Boujemaa" sort="Moubaraki, Boujemaa" uniqKey="Moubaraki B" first="Boujemaa" last="Moubaraki">Boujemaa Moubaraki</name>
</author>
<author><name sortKey="Sparkes, Hazel A" sort="Sparkes, Hazel A" uniqKey="Sparkes H" first="Hazel A." last="Sparkes">Hazel A. Sparkes</name>
</author>
<author><name sortKey="Batten, Stuart R" sort="Batten, Stuart R" uniqKey="Batten S" first="Stuart R." last="Batten">Stuart R. Batten</name>
</author>
<author><name sortKey="Murray, Keith S" sort="Murray, Keith S" uniqKey="Murray K" first="Keith S." last="Murray">Keith S. Murray</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:51A5236732D9FD366F5E79B45EC2C9673EE8A0EE</idno>
<date when="2013" year="2013">2013</date>
<idno type="doi">10.1002/ejic.201201075</idno>
<idno type="url">https://api.istex.fr/document/51A5236732D9FD366F5E79B45EC2C9673EE8A0EE/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">000F44</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000F44</idno>
<idno type="wicri:Area/Istex/Curation">000F44</idno>
<idno type="wicri:Area/Istex/Checkpoint">000267</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000267</idno>
<idno type="wicri:doubleKey">1434-1948:2013:Schneider C:spin:crossover:in</idno>
<idno type="wicri:Area/Main/Merge">004A81</idno>
<idno type="wicri:Area/Main/Curation">004957</idno>
<idno type="wicri:Area/Main/Exploration">004957</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Spin Crossover in a 3,5‐Bis(2‐pyridyl)‐1,2,4‐triazolate‐Bridged Dinuclear Iron(II) Complex [{Fe(NCBH<hi rend="subscript">3</hi>
)(py)}<hi rend="subscript">2</hi>
(μ‐L<hi rend="superscript">1</hi>
)<hi rend="subscript">2</hi>
] – Powder versus Single Crystal Study</title>
<author><name sortKey="Schneider, Caspar J" sort="Schneider, Caspar J" uniqKey="Schneider C" first="Caspar J." last="Schneider">Caspar J. Schneider</name>
<affiliation><wicri:noCountry code="subField">http://www.chem.monash.edu.au/staff/murray.html</wicri:noCountry>
</affiliation>
</author>
<author><name sortKey="Cashion, John D" sort="Cashion, John D" uniqKey="Cashion J" first="John D." last="Cashion">John D. Cashion</name>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Physics, Monash University, Clayton, Victoria 3800</wicri:regionArea>
<wicri:noRegion>Victoria 3800</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Chilton, Nicholas F" sort="Chilton, Nicholas F" uniqKey="Chilton N" first="Nicholas F." last="Chilton">Nicholas F. Chilton</name>
<affiliation><wicri:noCountry code="subField">http://www.chem.monash.edu.au/staff/murray.html</wicri:noCountry>
</affiliation>
</author>
<author><name sortKey="Etrillard, Celine" sort="Etrillard, Celine" uniqKey="Etrillard C" first="Céline" last="Etrillard">Céline Etrillard</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>CNRS, ICMCB, UPR 9048, 33600 Pessac</wicri:regionArea>
<wicri:noRegion>33600 Pessac</wicri:noRegion>
<wicri:noRegion>33600 Pessac</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Fuentealba, Mauricio" sort="Fuentealba, Mauricio" uniqKey="Fuentealba M" first="Mauricio" last="Fuentealba">Mauricio Fuentealba</name>
<affiliation wicri:level="1"><country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Chemistry, Durham University, South Road, Durham, DHI 3LE</wicri:regionArea>
<wicri:noRegion>DHI 3LE</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Howard, Judith A K" sort="Howard, Judith A K" uniqKey="Howard J" first="Judith A. K." last="Howard">Judith A. K. Howard</name>
<affiliation wicri:level="1"><country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Chemistry, Durham University, South Road, Durham, DHI 3LE</wicri:regionArea>
<wicri:noRegion>DHI 3LE</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Letard, Jean Rancois" sort="Letard, Jean Rancois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>CNRS, ICMCB, UPR 9048, 33600 Pessac</wicri:regionArea>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Milsmann, Carsten" sort="Milsmann, Carsten" uniqKey="Milsmann C" first="Carsten" last="Milsmann">Carsten Milsmann</name>
<affiliation wicri:level="4"><country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Chemistry, Princeton University, Princeton, New Jersey 08544</wicri:regionArea>
<orgName type="university">Université de Princeton</orgName>
<placeName><settlement type="city">Princeton (New Jersey)</settlement>
<region type="state">New Jersey</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Moubaraki, Boujemaa" sort="Moubaraki, Boujemaa" uniqKey="Moubaraki B" first="Boujemaa" last="Moubaraki">Boujemaa Moubaraki</name>
<affiliation><wicri:noCountry code="subField">http://www.chem.monash.edu.au/staff/murray.html</wicri:noCountry>
</affiliation>
</author>
<author><name sortKey="Sparkes, Hazel A" sort="Sparkes, Hazel A" uniqKey="Sparkes H" first="Hazel A." last="Sparkes">Hazel A. Sparkes</name>
<affiliation wicri:level="1"><country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Chemistry, Durham University, South Road, Durham, DHI 3LE</wicri:regionArea>
<wicri:noRegion>DHI 3LE</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Batten, Stuart R" sort="Batten, Stuart R" uniqKey="Batten S" first="Stuart R." last="Batten">Stuart R. Batten</name>
<affiliation><wicri:noCountry code="subField">http://www.chem.monash.edu.au/staff/murray.html</wicri:noCountry>
</affiliation>
</author>
<author><name sortKey="Murray, Keith S" sort="Murray, Keith S" uniqKey="Murray K" first="Keith S." last="Murray">Keith S. Murray</name>
<affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country>
</affiliation>
<affiliation></affiliation>
<affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j" type="main">European Journal of Inorganic Chemistry</title>
<title level="j" type="sub">Spin‐Crossover Complexes (Cluster Issue)</title>
<title level="j" type="alt">EUROPEAN JOURNAL OF INORGANIC CHEMISTRY</title>
<idno type="ISSN">1434-1948</idno>
<idno type="eISSN">1099-0682</idno>
<imprint><biblScope unit="vol">2013</biblScope>
<biblScope unit="issue">5‐6</biblScope>
<biblScope unit="page" from="850">850</biblScope>
<biblScope unit="page" to="864">864</biblScope>
<biblScope unit="page-count">15</biblScope>
<publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2013-02-18">2013-02-18</date>
</imprint>
<idno type="ISSN">1434-1948</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">1434-1948</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Apical ligands</term>
<term>Asymmetric unit</term>
<term>Australian synchrotron</term>
<term>B3lyp level</term>
<term>Behaviour</term>
<term>Bond lengths</term>
<term>Borshch</term>
<term>Bousseksou</term>
<term>Bulk powder</term>
<term>Centre</term>
<term>Chem</term>
<term>Coordination sphere</term>
<term>Crucial role</term>
<term>Crystal form</term>
<term>Crystal lattice</term>
<term>Crystal structure</term>
<term>Crystalline forms</term>
<term>Crystalline samples</term>
<term>Crystallographic data</term>
<term>Dalton trans</term>
<term>Density plots</term>
<term>Differential scanning calorimetry</term>
<term>Diffraction data</term>
<term>Dinuclear</term>
<term>Dinuclear complexes</term>
<term>Dinuclear molecule</term>
<term>Dinuclear molecules</term>
<term>Dinuclear systems</term>
<term>Doublet</term>
<term>Durham university</term>
<term>Energy difference</term>
<term>Experimental data</term>
<term>Experimental observation</term>
<term>Experimental parameters</term>
<term>Feii</term>
<term>Feii centre</term>
<term>Feii centres</term>
<term>Feii site</term>
<term>Feii sites</term>
<term>Full paper</term>
<term>Gmbh</term>
<term>Good agreement</term>
<term>Green laser</term>
<term>Ground sample</term>
<term>Inorg</term>
<term>Intermolecular interactions</term>
<term>Inversion centre</term>
<term>Isomer</term>
<term>Isomer shift</term>
<term>Isomer shifts</term>
<term>Kaizaki</term>
<term>Kgaa</term>
<term>Laser</term>
<term>Liesst</term>
<term>Liesst effect</term>
<term>Liesst state</term>
<term>Liesst studies</term>
<term>Ligand</term>
<term>Light irradiation</term>
<term>Light source</term>
<term>Lith effect</term>
<term>Magnetic properties</term>
<term>Magnetic susceptibility</term>
<term>Magnetic susceptibility data</term>
<term>Magnetic susceptibility studies</term>
<term>Metastable</term>
<term>Metastable state</term>
<term>Methanolic solution</term>
<term>Monash university</term>
<term>Moubaraki</term>
<term>Octahedral distortion parameter</term>
<term>Other dinuclear</term>
<term>Paper figure</term>
<term>Phenomenological model</term>
<term>Photoinduced metastable state</term>
<term>Phys</term>
<term>Plateau region</term>
<term>Powder diffraction</term>
<term>Powder form</term>
<term>Powder sample</term>
<term>Pxrd</term>
<term>Pxrd data</term>
<term>Pxrd measurements</term>
<term>Pxrd patterns</term>
<term>Pyridine</term>
<term>Quadrupole</term>
<term>Quadrupole splitting</term>
<term>Quantum chemical calculations</term>
<term>Raman</term>
<term>Raman spectra</term>
<term>Raman spectroscopic data</term>
<term>Relative energies</term>
<term>Room temperature</term>
<term>Second transition</term>
<term>Several weeks</term>
<term>Single crystal</term>
<term>Single crystals</term>
<term>Space group</term>
<term>Susceptibility</term>
<term>Thermal hysteresis</term>
<term>Thermogravimetric analysis</term>
<term>Triazolate ring</term>
<term>Unit cell volume</term>
<term>Verlag</term>
<term>Verlag gmbh</term>
<term>Version bruker</term>
<term>Weak bands</term>
<term>Weinheim</term>
</keywords>
<keywords scheme="Teeft" xml:lang="en"><term>Apical ligands</term>
<term>Asymmetric unit</term>
<term>Australian synchrotron</term>
<term>B3lyp level</term>
<term>Behaviour</term>
<term>Bond lengths</term>
<term>Borshch</term>
<term>Bousseksou</term>
<term>Bulk powder</term>
<term>Centre</term>
<term>Chem</term>
<term>Coordination sphere</term>
<term>Crucial role</term>
<term>Crystal form</term>
<term>Crystal lattice</term>
<term>Crystal structure</term>
<term>Crystalline forms</term>
<term>Crystalline samples</term>
<term>Crystallographic data</term>
<term>Dalton trans</term>
<term>Density plots</term>
<term>Differential scanning calorimetry</term>
<term>Diffraction data</term>
<term>Dinuclear</term>
<term>Dinuclear complexes</term>
<term>Dinuclear molecule</term>
<term>Dinuclear molecules</term>
<term>Dinuclear systems</term>
<term>Doublet</term>
<term>Durham university</term>
<term>Energy difference</term>
<term>Experimental data</term>
<term>Experimental observation</term>
<term>Experimental parameters</term>
<term>Feii</term>
<term>Feii centre</term>
<term>Feii centres</term>
<term>Feii site</term>
<term>Feii sites</term>
<term>Full paper</term>
<term>Gmbh</term>
<term>Good agreement</term>
<term>Green laser</term>
<term>Ground sample</term>
<term>Inorg</term>
<term>Intermolecular interactions</term>
<term>Inversion centre</term>
<term>Isomer</term>
<term>Isomer shift</term>
<term>Isomer shifts</term>
<term>Kaizaki</term>
<term>Kgaa</term>
<term>Laser</term>
<term>Liesst</term>
<term>Liesst effect</term>
<term>Liesst state</term>
<term>Liesst studies</term>
<term>Ligand</term>
<term>Light irradiation</term>
<term>Light source</term>
<term>Lith effect</term>
<term>Magnetic properties</term>
<term>Magnetic susceptibility</term>
<term>Magnetic susceptibility data</term>
<term>Magnetic susceptibility studies</term>
<term>Metastable</term>
<term>Metastable state</term>
<term>Methanolic solution</term>
<term>Monash university</term>
<term>Moubaraki</term>
<term>Octahedral distortion parameter</term>
<term>Other dinuclear</term>
<term>Paper figure</term>
<term>Phenomenological model</term>
<term>Photoinduced metastable state</term>
<term>Phys</term>
<term>Plateau region</term>
<term>Powder diffraction</term>
<term>Powder form</term>
<term>Powder sample</term>
<term>Pxrd</term>
<term>Pxrd data</term>
<term>Pxrd measurements</term>
<term>Pxrd patterns</term>
<term>Pyridine</term>
<term>Quadrupole</term>
<term>Quadrupole splitting</term>
<term>Quantum chemical calculations</term>
<term>Raman</term>
<term>Raman spectra</term>
<term>Raman spectroscopic data</term>
<term>Relative energies</term>
<term>Room temperature</term>
<term>Second transition</term>
<term>Several weeks</term>
<term>Single crystal</term>
<term>Single crystals</term>
<term>Space group</term>
<term>Susceptibility</term>
<term>Thermal hysteresis</term>
<term>Thermogravimetric analysis</term>
<term>Triazolate ring</term>
<term>Unit cell volume</term>
<term>Verlag</term>
<term>Verlag gmbh</term>
<term>Version bruker</term>
<term>Weak bands</term>
<term>Weinheim</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract">The structural characteristics and physical properties of the 3,5‐bis(2‐pyridyl)‐1,2,4‐triazolate (L1) bridged dinuclear iron(II) spin‐crossover complex [{Fe(NCBH3)(py)}2(μ‐L1)2] (1) in both powder (1p) and single crystal (1c) forms have been investigated. Both forms of [{Fe(NCBH3)(py)}2(μ‐L1)2] display a thermally induced spin transition; however, the transitions have different T1/2 values and different degrees of spin conversion. Both forms display the photomagnetic light‐induced excited spin‐state trapping (LIESST) effect as well as reverse LIESST and have been compared by Raman spectral and powder X‐ray diffraction methods, which indicate that they are polymorphs. The single crystal form 1c shows a “half” spin transition and has been further characterised at temperatures above and below the spin transition by low temperature crystallographic methods including single crystal LIESST experiments (at 40 K) and by Mössbauer spectroscopy; thus, the nature of the [HS‐LS] form and the different spin isomers were revealed. To complement the experimental results, compound 1 and several other related FeII dinuclear spin‐crossover compounds have been evaluated by quantum‐chemical DFT calculations. Additionally, the susceptibilities for the powder form 1p, which displays a complete two‐step spin‐crossover, were also fitted to a phenomenological model for dinuclear spin‐crossover complexes.</div>
</front>
</TEI>
<affiliations><list><country><li>Australie</li>
<li>France</li>
<li>Royaume-Uni</li>
<li>États-Unis</li>
</country>
<region><li>Aquitaine</li>
<li>New Jersey</li>
<li>Nouvelle-Aquitaine</li>
</region>
<settlement><li>Pessac</li>
<li>Princeton (New Jersey)</li>
</settlement>
<orgName><li>Université de Princeton</li>
</orgName>
</list>
<tree><noCountry><name sortKey="Batten, Stuart R" sort="Batten, Stuart R" uniqKey="Batten S" first="Stuart R." last="Batten">Stuart R. Batten</name>
<name sortKey="Chilton, Nicholas F" sort="Chilton, Nicholas F" uniqKey="Chilton N" first="Nicholas F." last="Chilton">Nicholas F. Chilton</name>
<name sortKey="Moubaraki, Boujemaa" sort="Moubaraki, Boujemaa" uniqKey="Moubaraki B" first="Boujemaa" last="Moubaraki">Boujemaa Moubaraki</name>
<name sortKey="Schneider, Caspar J" sort="Schneider, Caspar J" uniqKey="Schneider C" first="Caspar J." last="Schneider">Caspar J. Schneider</name>
</noCountry>
<country name="Australie"><noRegion><name sortKey="Cashion, John D" sort="Cashion, John D" uniqKey="Cashion J" first="John D." last="Cashion">John D. Cashion</name>
</noRegion>
</country>
<country name="France"><noRegion><name sortKey="Etrillard, Celine" sort="Etrillard, Celine" uniqKey="Etrillard C" first="Céline" last="Etrillard">Céline Etrillard</name>
</noRegion>
<name sortKey="Letard, Jean Rancois" sort="Letard, Jean Rancois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name>
</country>
<country name="Royaume-Uni"><noRegion><name sortKey="Fuentealba, Mauricio" sort="Fuentealba, Mauricio" uniqKey="Fuentealba M" first="Mauricio" last="Fuentealba">Mauricio Fuentealba</name>
</noRegion>
<name sortKey="Howard, Judith A K" sort="Howard, Judith A K" uniqKey="Howard J" first="Judith A. K." last="Howard">Judith A. K. Howard</name>
<name sortKey="Sparkes, Hazel A" sort="Sparkes, Hazel A" uniqKey="Sparkes H" first="Hazel A." last="Sparkes">Hazel A. Sparkes</name>
</country>
<country name="États-Unis"><region name="New Jersey"><name sortKey="Milsmann, Carsten" sort="Milsmann, Carsten" uniqKey="Milsmann C" first="Carsten" last="Milsmann">Carsten Milsmann</name>
</region>
<name sortKey="Murray, Keith S" sort="Murray, Keith S" uniqKey="Murray K" first="Keith S." last="Murray">Keith S. Murray</name>
<name sortKey="Murray, Keith S" sort="Murray, Keith S" uniqKey="Murray K" first="Keith S." last="Murray">Keith S. Murray</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Asie/explor/AustralieFrV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 004957 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 004957 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Asie
   |area=    AustralieFrV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     ISTEX:51A5236732D9FD366F5E79B45EC2C9673EE8A0EE
   |texte=   Spin Crossover in a 3,5‐Bis(2‐pyridyl)‐1,2,4‐triazolate‐Bridged Dinuclear Iron(II) Complex [{Fe(NCBH3)(py)}2(μ‐L1)2] – Powder versus Single Crystal Study
}}

This area was generated with Dilib version V0.6.33.
Data generation: Tue Dec 5 10:43:12 2017. Site generation: Tue Mar 5 14:07:20 2024

	Serveur d'exploration sur les relations entre la France et l'Australie
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur les relations entre la France et l'Australie

Spin Crossover in a 3,5‐Bis(2‐pyridyl)‐1,2,4‐triazolate‐Bridged Dinuclear Iron(II) Complex [{Fe(NCBH3)(py)}2(μ‐L1)2] – Powder versus Single Crystal Study

Spin Crossover in a 3,5‐Bis(2‐pyridyl)‐1,2,4‐triazolate‐Bridged Dinuclear Iron(II) Complex [{Fe(NCBH3)(py)}2(μ‐L1)2] – Powder versus Single Crystal Study

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri